Limitations of model-fitting methods for kinetic analysis: Polystyrene thermal degradation

Limitations of model fitting methods for lensing shear estimation

Gravitational lensing shear has the potential to be the most powerful tool for constraining the nature of dark energy. However, accurate measurement of galaxy shear is crucial and has been shown to be non-trivial by the Shear TEsting Programme. Here we demonstrate a fundamental limit to the accuracy achievable by model-fitting techniques, if oversimplistic models are used. We show that even if ...

Model-Fitting Approach to Kinetic Analysis of Non-Isothermal Oxidation of Molybdenite

The kinetics of molybdenite oxidation was studied by non-isothermal TGA-DTA with heating rate 5 ºC.min-1.The model-fitting kinetic approach applied to TGA data .The Coats-Redfern method used for model fitting. The popular model-fitting gives excellent fit for non-isothermal data in chemically controlled regime. The apparent activation energy was determined to be about 34.2 kcalmo...

Kinetic equations for thermal degradation of polymers

Kinetic equations are analyzed for thermal degradation of polymers. The governing relations are based on the fragmentation–annihilation concept. Explicit solutions to these equations are derived in two particular cases of interest. For arbitrary values of adjustable parameters, the evolution of the number-average and mass-average molecular weights of polymers is analyzed numerically. Good agree...

Combined Kinetic Analysis of Thermal Degradation of Polymeric Materials under Any Thermal Pathway

Combined kinetic analysis has been applied for the first time to the thermal degradation of polymeric materials. The combined kinetic analysis allows the determination of the kinetic parameter from the simultaneous analysis of a set of experimental curves recorded under any thermal schedule. Besides, the method does not make any assumption about the kinetic model or activation energy and allows...

Application of Numerical Methods in the Analysis of Mat Foundations and Limitations of Classical Methods